I don't know what the relation in your problem is, but I'll just explain this using my own example.
Let's use the following relation as the example (pretend it's a table of values):
x | y
0 | 1
2 | 4
4 | 7
6 | 10
To write the relation as ordered pairs, you need the x and y values from the table. An ordered pair is written like this: (x,y).
Based off of this explanation, the ordered pairs from this example would be:
(0,1) (2,4) (4,7) (6,10)
